III.

Effects of Acid Rain

The acids in acid rain react chemically with any object they contact. Acids are corrosive chemicals that react with other chemicals by giving up hydrogen atoms. The acidity of a substance comes from the abundance of free hydrogen atoms when the substance is dissolved in water. Acidity is measured using a pH scale with units from 0 to 14. Acidic substances have pH numbers from 1 to 6—the lower the pH number, the stronger, or more corrosive, the substance. Some nonacidic substances, called bases or alkalis, are like acids in reverse—they readily accept the hydrogen atoms that the acids offer. Bases have pH numbers from 8 to 14, with the higher values indicating increased alkalinity. Pure water has a neutral pH of 7—it is not acidic or basic. Rain, snow, or fog with a pH below 5.6 is considered acid rain.

When bases mix with acids, the bases lessen the strength of an acid (see Acids and Bases). This buffering action regularly occurs in nature. Rain, snow, and fog formed in regions free of acid pollutants are slightly acidic, having a pH near 5.6. Alkaline chemicals in the environment, found in rocks, soils, lakes, and streams, regularly neutralize this precipitation. But when precipitation is highly acidic, with a pH below 5.6, naturally occurring acid buffers become depleted over time, and nature’s ability to neutralize the acids is impaired. Acid rain has been linked to widespread environmental damage, including soil and plant degradation, depleted life in lakes and streams, and erosion of human-made structures.

A.

Soil

In soil, acid rain dissolves and washes away nutrients needed by plants. It can also dissolve toxic substances, such as aluminum and mercury, which are naturally present in some soils, freeing these toxins to pollute water or to poison plants that absorb them. Some soils are quite alkaline and can neutralize acid deposition indefinitely; others, especially thin mountain soils derived from granite or gneiss, buffer acid only briefly.

B.

Trees

By removing useful nutrients from the soil, acid rain slows the growth of plants, especially trees. It also attacks trees more directly by eating holes in the waxy coating of leaves and needles, causing brown dead spots. If many such spots form, a tree loses some of its ability to make food through photosynthesis. Also, organisms that cause disease can infect the tree through its injured leaves. Once weakened, trees are more vulnerable to other stresses, such as insect infestations, drought, and cold temperatures.

Spruce and fir forests at higher elevations, where the trees literally touch the acid clouds, seem to be most at risk. Acid rain has been blamed for the decline of spruce forests on the highest ridges of the Appalachian Mountains in the eastern United States. In the Black Forest of southwestern Germany, half of the trees are damaged from acid rain and other forms of pollution.

C.

Agriculture

Most farm crops are less affected by acid rain than are forests. The deep soils of many farm regions, such as those in the Midwestern United States, can absorb and neutralize large amounts of acid. Mountain farms are more at risk—the thin soils in these higher elevations cannot neutralize so much acid. Farmers can prevent acid rain damage by monitoring the condition of the soil and, when necessary, adding crushed limestone to the soil to neutralize acid. If excessive amounts of nutrients have been leached out of the soil, farmers can replace them by adding nutrient-rich fertilizer.

D.

Surface Waters

Acid rain falls into and drains into streams, lakes, and marshes. Where there is snow cover in winter, local waters grow suddenly more acidic when the snow melts in the spring. Most natural waters are close to chemically neutral, neither acidic nor alkaline: their pH is between 6 and 8. In the northeastern United States and southeastern Canada, the water in some lakes now has a pH value of less than 5 as a result of acid rain. This means they are at least ten times more acidic than they should be. In the Adirondack Mountains of New York State, a quarter of the lakes and ponds are acidic, and many have lost their brook trout and other fish. In the middle Appalachian Mountains, over 1,300 streams are afflicted. All of Norway’s major rivers have been damaged by acid rain, severely reducing salmon and trout populations.

E.

Plants and Animals

The effects of acid rain on wildlife can be far-reaching. If a population of one plant or animal is adversely affected by acid rain, animals that feed on that organism may also suffer. Ultimately, an entire ecosystem may become endangered. Some species that live in water are very sensitive to acidity, some less so. Freshwater clams and mayfly young, for instance, begin dying when the water pH reaches 6.0. Frogs can generally survive more acidic water, but if their supply of mayflies is destroyed by acid rain, frog populations may also decline. Fish eggs of most species stop hatching at a pH of 5.0. Below a pH of 4.5, water is nearly sterile, unable to support any wildlife.

Land animals dependent on aquatic organisms are also affected. Scientists have found that populations of snails living in or near water polluted by acid rain are declining in some regions. In The Netherlands songbirds are finding fewer snails to eat. The eggs these birds lay have weakened shells because the birds are receiving less calcium from snail shells.

F.

Human-Made Structures

Acid rain and the dry deposition of acidic particles damage buildings, statues, automobiles, and other structures made of stone, metal, or any other material exposed to weather for long periods. The corrosive damage can be expensive and, in cities with very historic buildings, tragic. Both the Parthenon in Athens, Greece, and the Taj Mahal in Agra, India, are deteriorating due to acid pollution.

G.

Human Health

The acidification of surface waters causes little direct harm to people. It is safe to swim in even the most acidified lakes. However, toxic substances leached from soil can pollute local water supplies. In Sweden, as many as 10,000 lakes have been polluted by mercury released from soils damaged by acid rain, and residents have been warned to avoid eating fish caught in these lakes. In the air, acids join with other chemicals to produce urban smog, which can irritate the lungs and make breathing difficult, especially for people who already have asthma, bronchitis, or other respiratory diseases. Solid particles of sulfates, a class of minerals derived from sulfur dioxide, are thought to be especially damaging to the lungs.

H.

Acid Rain and Global Warming

Acid pollution has one surprising effect that may be beneficial. Sulfates in the upper atmosphere reflect some sunlight out into space, and thus tend to slow down global warming. Scientists believe that acid pollution may have delayed the onset of warming by several decades in the middle of the 20th century.