II.

How Diamonds Form

Diamonds are crystals composed of pure carbon. In nature, diamond crystallizes from hot carbon-rich fluids. This crystallization requires tremendous heat and pressure—1000 to 1200°C (1800 to 2200°F) of heat and 50 kilobars of pressure. (One bar is based on the pressure the atmosphere exerts at sea level, about 1.02 kg per sq cm, or 14.7 lb per sq in; 50 kilobars is 50,000 bars.) The pressures and temperatures at which natural diamond forms only occur deep underground. Scientists believe that diamonds form at depths greater than 150 km (93 mi), and there is evidence that some diamonds formed as deep as 670 km (420 mi) beneath Earth’s surface.

Concentrations of diamonds great enough to be economically feasible for mining are usually found in Earth’s oldest continental regions, called cratons. Cratons form the cores of most continents and consist of inactive geological areas more than 2 billion years old with thick crust and deep roots extending into the mantle beneath. Craton conditions are ideal for diamond formation and preservation. Scientists have determined the ages of some diamonds by dating mineral impurities trapped within the diamonds. These data reveal that most cratonic diamonds are ancient, some older than 3 billion years.

Much younger volcanic rocks—kimberlites and lamproites—pass through the cratonic rocks in a liquid form called magma during their rapid ascent to Earth’s surface. These flowing veins of rock act as carriers of diamonds and other rock fragments. After eruption they solidify, forming funnel-shaped kimberlite “pipes.” These pipes are primary diamond deposits. Many diamonds are recovered at a distance from their primary deposits in secondary alluvial deposits, which are loose eroded materials left behind by flowing water. In some instances diamonds are also found in sandstones, conglomerates, and other sedimentary rocks that presumably solidified from former alluvial deposits. Wind and glaciers can also transport diamonds from their point of origin at Earth’s surface.

Small, generally low quality diamonds form in rocks at shallower depths under pressure conditions that are higher than usual for those depths. Tectonic movement, rather than magma, transports these diamonds to Earth’s surface. Deposits of this type occur in areas such as Kazakhstan and typically involve the collision of a continental and an oceanic plate followed by rapid uplift of deeply buried rocks. Diamond deposits brought to the surface by tectonic movement are generally younger than kimberlitic diamonds, and typically consist of microdiamonds (less than 1 mm across) or graphite relics of larger diamonds.

Diamonds are also found in meteorites and near meteorite craters on Earth’s surface. Extremely small diamonds (nanodiamonds) occur in many types of meteorites and have a lower density than other diamonds. Meteorites can also produce pressure and heat at the moment of impact sufficient to transform carbon into diamond. Diamond found in a type of meteorite called ureilite is thought to form directly from graphite contained in the meteorites upon impact. Impact-crater diamonds are opaque and range from very small to around a centimeter in diameter.

Black diamonds called carbonados are thought to have an extraterrestrial origin, as well. These diamonds are only found in 1.5-billion-year-old geologic formations in Brazil and in the Central African Republic, regions that were connected as part of one land mass at the time. Carbonados are not associated with volcanic rock or other types of diamonds. A study published in 2006 established that their chemistry is unlike that of diamonds formed on Earth. Infrared analysis of the carbonado samples indicated that the minerals may have formed in a supernova explosion between 2.6 billion to 3.8 billion years ago. The black diamonds might have come to Earth inside meteorites.